Spark Plasma Sintering of Si3N4 Ceramics with Y2O3–Al2O3 (3%–10% wt.) as Sintering Additive

نویسندگان

چکیده

The ceramic samples fabricated by spark plasma sintering of powder mixtures based on silicon nitride (Si3N4) were investigated. made wet chemical methods from commercial α-Si3N4 (the particle size <5 μm) and Y2O3-Al2O3 additive (3% to 10% wt.). Sintering was carried out at the heating rate 50 °C/min load 70 MPa until shrinkage end. characterized scanning electron microscopy X-ray diffraction. during analyzed, activation energy calculated according Young-Cutler model. density, microhardness, fracture toughness also measured. All had high relative densities (98%–99%), Vickers microhardness 15.5–17.4 GPa, Palmquist toughness, 3.8–5.1 MPa∙m1/2. An increase in amount led a decrease temperature mixtures. β-Si3N4 ceramics decreased monotonically with increasing additive. did not zero when maximum compaction reached 3% wt. On contrary, it increased sharply due beginning Si3N4 decomposition.

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ژورنال

عنوان ژورنال: Coatings

سال: 2023

ISSN: ['2079-6412']

DOI: https://doi.org/10.3390/coatings13020240