Spark Plasma Sintering of Si3N4 Ceramics with Y2O3–Al2O3 (3%–10% wt.) as Sintering Additive
نویسندگان
چکیده
The ceramic samples fabricated by spark plasma sintering of powder mixtures based on silicon nitride (Si3N4) were investigated. made wet chemical methods from commercial α-Si3N4 (the particle size <5 μm) and Y2O3-Al2O3 additive (3% to 10% wt.). Sintering was carried out at the heating rate 50 °C/min load 70 MPa until shrinkage end. characterized scanning electron microscopy X-ray diffraction. during analyzed, activation energy calculated according Young-Cutler model. density, microhardness, fracture toughness also measured. All had high relative densities (98%–99%), Vickers microhardness 15.5–17.4 GPa, Palmquist toughness, 3.8–5.1 MPa∙m1/2. An increase in amount led a decrease temperature mixtures. β-Si3N4 ceramics decreased monotonically with increasing additive. did not zero when maximum compaction reached 3% wt. On contrary, it increased sharply due beginning Si3N4 decomposition.
منابع مشابه
Processing, Mechanical and Optical Properties of Additive-Free ZrC Ceramics Prepared by Spark Plasma Sintering
In the present study, nearly fully dense monolithic ZrC samples are produced and broadly characterized from microstructural, mechanical and optical points of view. Specifically, 98% dense products are obtained by Spark Plasma Sintering (SPS) after 20 min dwell time at 1850 °C starting from powders preliminarily prepared by Self-propagating High-temperature Synthesis (SHS) followed by 20 min bal...
متن کاملComparison of Creep Behavior in Alumina Based Ceramics Densified by Spark Plasma Sintering and Hot Pressing
Spark plasma sintering (SPS) method, as plasma activated sintering, is a method applicable for rapid sintering of metals and ceramics. Owing to the advantage of rapid heating, the alumina ceramics obtained by SPS have a grain size and density comparable to those of hot pressed ones. The increase of densification rate may be related to some difference in ion transport characteristics. This study...
متن کاملEffect of Sintering Temperature on Structural, Dielectric, and Magnetic Properties of Multiferroic YFeO3 Ceramics Fabricated by Spark Plasma Sintering
Based on precursor powders with a size of 200-300 nm prepared by the low-temperature solid reaction method, phase-pure YFeO₃ ceramics are fabricated using spark plasma sintering (SPS) at different temperatures. X-ray diffraction (XRD) and scanning electron microscopy (SEM) reveal that the high-purity YFeO₃ ceramics can be prepared using SPS, while the results from X-ray photoelectron spectrosco...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Coatings
سال: 2023
ISSN: ['2079-6412']
DOI: https://doi.org/10.3390/coatings13020240